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      When Wallace Carothers invented nylon, he made a polymer with a structure similar to that of silk. Natural materials inspired his work, and now we're going to take a look at some of those natural polymers.

      polyisoprene structure

      Rubber

      Natural rubber is one of the more unusual materials found in nature. It can be stretched and it snaps back to its original shape. It's also waterproof. What more could anyone want? A lot of different plants produce rubber, but the most important is the hevea tree (hevea brasiliensis). Natural rubber's scientific name is polyisoprene, and it has a repeat unit like you see on your right.

      Starch and Cellulose

      Starch and cellulose are both made from the same monomer, glucose. Glucose is a simple kind of sugar that your body uses for fuel. Starch is found in foods like bread, potatoes, corn, and rice. Your body breaks it down to get the glucose it needs.

      On the other hand, cellulose is a polymer we can't digest. It is the main component of cotton and wood (and therefore paper), and it makes very strong fibers. Also, even though we can't digest cellulose, certain animals can. Termites can digest the cellulose in wood, while cattle and sheep happily get their nourishment from the cellulose in grass.

      Proteins

      Proteins are the family of polymers that inspired nylon. Wallace Carothers suspected that silk, one kind of protein, was a polyamide. So he decided to make a synthetic polyamide when he set out to make a synthetic fiber. But silk is just one kind of protein. Your skin, hair, and fingernails are made of a protein called keratin. In your blood, a protein called hemoglobin carries oxygen to your cells, while other proteins called antibodies fight disease. One amazing family of proteins are the enzymes. Enzymes are catalysts; that is, they speed up chemical reactions in your body. Some of them can make chemical reactions take place a million times faster than they would without an enzyme.

      amino acids and proteins

      The body polymerizes amino acids to make proteins.

      Like nylon, proteins are polyamides. They have a repeat structure like you see above. However, unlike nylon, each repeat unit in a protein may be different. Your body builds proteins from twenty different amino acids. The group R in the diagram above is different in each amino acid. A given protein may contain all twenty, in a precise sequence consisting of thousands of amino acid repeat units. The number of possible combinations and sequences is endless. With this much possible variety, its easy to see why there are so many different proteins and why they can do so many different things.

      Since proteins do so many different jobs in the body, it's no wonder that Linneaus Dorman decided to see if it was possible to make synthetic proteins to make the body work even better.

      DNA and RNA

      Deoxyribonucleic acid (DNA) and ribonucleic acid (RNA) are polymers we can't live without. The DNA is the blueprint that determines everything about your body. DNA is passed from parents to their children, so children inherit the physical characteristics of their parents. RNA helps the blueprints of DNA to be carried out.

        Next: Meet Linneaus Dorman


      For more information, at other Web sites...

        Natural Polymers — part of The Macrogalleria from the University of Southern Mississippi.

        The Story of Rubber — a polymer expedition from the Polymer Science Learning Center at the University of Southern Mississippi.


      Copyright ©2001 The Chemical Heritage Foundation