Stephanie L. Kwolek

Stephanie Kwolek at a polarizing microscope. Gift of Stephanie Kwolek. Courtesy DuPont.

Stephanie Kwolek at a polarizing microscope. Gift of Stephanie Kwolek. Courtesy DuPont.

In 1965 Stephanie L. Kwolek (1923–2014) succeeded in creating the first of a family of synthetic fibers of exceptional strength and stiffness. The best known member is Kevlar, a material used in fragmentation-resistant vests as well as in boats, airplanes, ropes, cables, tires, tennis racquets, skis, and so forth—in total about 200 applications.

Kwolek was born in New Kensington, Pennsylvania. Her father, who died when she was 10 years old, was a naturalist by avocation. She spent many hours with him exploring the woods and fields near her home and filling scrapbooks with leaves, wildflowers, seeds, grasses, and pertinent descriptions. From her mother, first a homemaker and then by necessity a career woman, Kwolek inherited a love of fabrics and sewing. At one time she thought she might become a fashion designer, but her mother warned her she would probably starve in that business because she was such a perfectionist. Later Kwolek became interested in teaching and then in chemistry and medicine.

When she graduated from the women’s college (Margaret Morrison Carnegie College) of Carnegie-Mellon University, she applied for a position as a chemist with the DuPont Company, among other places. Her job interview with W. Hale Charch, who had invented the process to make cellophane waterproof and who was by then a research director, was a memorable one. After Charch indicated that he would let her know in about two weeks whether she would be offered a job, Kwolek asked him if he could possibly make a decision sooner since she had to reply shortly to another offer. Charch called in his secretary and in Kwolek’s presence dictated an offer letter. In later years, she suspected that her assertiveness influenced his decision in her favor. At DuPont the polymer research she worked on was so interesting and challenging that she decided to drop her plans for medical school and make chemistry a lifetime career.

Stephanie Kwolek and others of the group that developed Kevlar. Gift of Stephanie Kwolek. Courtesy DuPont.

Stephanie Kwolek and others of the group that developed Kevlar. Left to right, Kwolek, Herbert Blades, Paul W. Morgan, and Joseph L. Rivers, Jr. Gift of Stephanie Kwolek. Courtesy DuPont.

She was engaged in several projects, including a search for new polymers as well as a new condensation process that takes place at lower temperatures—about 0˚ to 40˚C. The melt condensation polymerization process used in preparing nylon, for example, was instead done at more than 200˚C. The lower-temperature polycondensation processes, which employ very fast-reacting intermediates, make it possible to prepare polymers that cannot be melted and only begin to decompose at temperatures above 400°C.

Kwolek was in her 40s when she was asked by DuPont to scout for the next generation of fibers capable of performing in extreme conditions. This assignment involved preparing intermediates, synthesizing aromatic polyamides of high molecular weight, dissolving the polyamides in solvents, and spinning these solutions into fibers. She unexpectedly discovered that under certain conditions large numbers of the molecules of these rod-like polyamides become lined up in parallel, that is, form liquid crystalline solutions, and that these solutions can be spun directly into oriented fibers of very high strength and stiffness. These polyamide solutions were unlike any polymer solutions previously prepared in the laboratory. They were unusually fluid, turbid, and buttermilk-like in appearance, and became opalescent when stirred. The person in charge of the spinning equipment initially refused to spin the first such solution because he feared that the turbidity was caused by the presence of particles that would plug the tiny holes (0.001 inch in diameter) in the spinneret. He was finally persuaded to spin, and much to his surprise, strong, stiff fibers were obtained with no difficulty. Following this breakthrough many fibers were spun from liquid crystalline solutions, including the yellow Kevlar fiber.

Stephanie Kwolek. Courtesy DuPont.

Stephanie Kwolek. Courtesy DuPont.

Kwolek has received many awards for her invention of the technology behind Kevlar fiber, including induction into the National Inventors Hall of Fame in 1994 as only the fourth woman member of 113. In 1996 she received the National Medal of Technology, and in 1997 the Perkin Medal, presented by the American Section of the Society of Chemical Industry—both honors rarely awarded to women. She has served as a mentor for other women scientists and participated in programs that introduce young children to science. One of Kwolek’s most cited papers, written with Paul W. Morgan, is “The Nylon Rope Trick” (Journal of Chemical Education, April 1959, 36:182–184). It describes how to demonstrate condensation polymerization in a beaker at atmospheric pressure and room temperature—a demonstration now common in classrooms across the nation.

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